On Earth, in North America, the general rule is that white and yellow berries are poisonous, blue and purple are fine and red can go either way.How would he be able to decide what is ok to eat - short of trying everything? At the moment his diet seems to just be meat because he can cook that. But what about fruit/berries?
The customary test is to take a berry and crush it on the back of your hand. A reaction means don't eat it. After an hour with no reaction, touch the crushed berry to the outer lips. If still no reaction for another hour, touch it to the tongue. If it's bitter, spit it out. Otherwise, no reaction for two more hours, eat one berry. Wait 24 hours. If no reaction, they should be safe.
The same testing works for all plant materials (as well as insacts), though fruits/berries/nuts/seeds, shoots and roots are usually the more nutritious and useful parts. Many plants have perfectly edible roots and poisonous fruit or vice-versa.
The other thing is watch what mammals eat. Birds and reptiles can often eat things poisonous to mammals so don't rely on them.
Jeff